Potential of Sweet Corn Stem Biomass as Biosorbent in Adsorption of Mercury (Hg) Metal Contaminants
Muhammad Fathurrahman(a*), Sutanto(a), Yobi Sukresna(a)

(a) Department of Chemistry, Faculty of Mathematics and Natural Science, Universitas Pakuan, Jl. Pakuan PO BOX 452, Bogor 16143, West Java, Indonesia
* fathur110590[at]unpak.ac.id

Abstract

Corn stalks are an agricultural waste that is commonly found in Indonesia. Corn stalks have a high enough cellulose content which has functional groups that can be used as biosorbents. This study aims to optimize adsorption of corn stalk waste to mercury metal ions and then determine the adsorption capacity and adsorption constant of the Langmuir and Freundlich isotherm model. This research begins with corn stalk preparation, delignification, characterization using FTIR and SEM, determination of optimization of biosorbent weight, pH of Hg solution, contact time, and concentration of Hg solution, then applied to mercury metal contamination waste. Optimization of weight of biosorbent in the range 0.4-1.2 grams, pH of the Hg solution is 2-4, contact time is 60-120 minutes, and concentration of the Hg solution of 30-100 g/L with a solution volume of 50 mL. Furthermore, determination of mercury levels, manufacture of standard series, and testing using ICP-OES. Followed by determination of Langmuir and Freundlich adsorption isothermal model. The results of this study indicate that the optimum conditions for adsorption process occur at the weight of the biosorbent 1.2 grams, pH of the Hg 3 solution, contact time of 90 minutes and concentration of Hg solution of 40 ppb with a solution volume of 50 mL. The application of biosorbent to metal contamination waste with adsorbed Hg concentration obtained 27.5772 ppb in 50 mL of waste solution with an adsorption efficiency of 88.44%. In determination of Langmuir and Freundlich isothermals, a match was found for Langmuir adsorption isothermals with &#61537- value or adsorption capacity of 0.00333 mg Hg/g biosorbent and &#61538- 176.8256.

Keywords: Corn stalk waste, Biosorbent, Adsorption, Optimization, Langmuir and Freundlich isothermal

Topic: Environmental Chemistry and Engineering